Richard Levi also got into the act as the opening pair registered a half-century partnership in quick time before Ian Butler dismissed the Gemini skipper.
Virender Sehwag, the Gemini Arabians skipper, looked at his vintage best as he dealt in big hits regularly.
Jacques Kallis, who was leading Libra Legends in the absence of Sourav Ganguly, won the toss and asked the opposition to bat first.
Richard Levi continued in a solid manner to bring up a fine half-century.
Richard Levi put on a good stand with Kumar Sangakkara before getting out.
Kumar Sangakkara, who took Gemini closer to 200, fell 14 short of a well-deserved ton.
Libra Legends slipped to 43 for 4 early on in their chase of 235.
Ryan Ten Doeschate (57) fought hard but failed to prevent a 78-run loss.